Help needed on Outlook Express

hi all,

I set up my work email at home on Outlook Express and I can receive emails easily with no hassles but i have a problem at sending email. I get the following error

First of all i disabled norton antivirus and internet security to see if there was any interference and I still had the same error. The other idea i had in mind is that either my isp i use at home is blocking port 25 or the mail server is blocking it?is there a way to quick check which port could be used for smtp port?but its strange because i use the same port 25 at work and it works fine so i think it could be my isp at home which is not letting it.

Any ideas or help would be great and thanks for everyone looking at it.